SUMMARY OF PM7 CALCULATION, Site No: 23746 MOPAC2016 (Version: 21.055M) Wed Feb 24 14:03:07 2021 No. of days remaining = 365 Empirical Formula: Pt6 Cl12 = 18 atoms MERS=(1,1,1) CHARGE=0 OUTPUT THREADS=1 PM7 GRADIENTS NOTXT EF Platinum(ii) chloride (PtCl2) h=-29.5 hr=crc GEOMETRY OPTIMISED USING EIGENVECTOR FOLLOWING (EF). SCF FIELD WAS ACHIEVED HEAT OF FORMATION = 3.50348 KCAL/MOL = 14.65855 KJ/MOL H.o.F. per unit cell = 0.58391 KCAL, for 6 unit cells, unit cell = Pt1 Cl2 TOTAL ENERGY = -6248.24874 EV ELECTRONIC ENERGY = -16553756.53077 EV CORE-CORE REPULSION = 16547508.28203 EV VOLUME OF UNIT CELL = 413.855 CUBIC ANGSTROMS DENSITY = 6.404 GRAMS/CC A = 8.088 ANGSTROMS B = 8.129 ANGSTROMS C = 8.058 ANGSTROMS ALPHA = 109.498 DEGREES BETA = 71.472 DEGREES GAMMA = 70.827 DEGREES GRADIENT NORM = 14.56489 = 3.43298 PER ATOM NO. OF FILLED LEVELS = 72 IONIZATION POTENTIAL = 8.757106 EV HOMO LUMO ENERGIES (EV) = -8.757 -2.294 MOLECULAR WEIGHT = 1595.9760 Pressure required to constrain translation vectors Tv( 19) Pressure: 0.42 GPa Tv( 20) Pressure: 0.47 GPa Tv( 21) Pressure: 1.49 GPa SCF CALCULATIONS = 24 WALL-CLOCK TIME = 12 MINUTES AND 17.402 SECONDS COMPUTATION TIME = 12 MINUTES AND 8.717 SECONDS FINAL GEOMETRY OBTAINED MERS=(1,1,1) CHARGE=0 OUTPUT THREADS=1 PM7 GRADIENTS NOTXT EF Platinum(ii) chloride (PtCl2) h=-29.5 hr=crc Pt -8.12832873 +1 -0.00136417 +1 0.00194571 +1 Pt -5.38557439 +1 1.96643432 +1 0.01201417 +1 Pt -6.25378363 +1 0.27159620 +1 2.80624972 +1 Pt -3.51100114 +1 -0.65139657 +1 1.06181303 +1 Pt -6.25599495 +1 -2.61914966 +1 1.05323473 +1 Cl -4.00706689 +1 -2.85926166 +1 1.54660601 +1 Cl -6.66375718 +1 -1.96610564 +1 3.23622206 +1 Cl -4.00557944 +1 -0.05996982 +1 3.24480843 +1 Cl -7.63271067 +1 2.20665876 +1 -0.48112783 +1 Cl -4.97478635 +1 1.31390703 +1 -2.16992718 +1 Cl -7.63339721 +1 -0.59278777 +1 -2.18103554 +1 Cl -5.81725758 +1 2.45605672 +1 2.22137473 +1 Cl -3.17841748 +1 -1.21114888 +1 -1.14812812 +1 Cl -8.46202852 +1 -2.22016403 +1 0.52478221 +1 Cl -5.82421232 +1 -3.10830570 +1 -1.15658118 +1 Cl -8.46080758 +1 0.55906609 +1 2.21196217 +1 Cl -3.17708009 +1 1.56653750 +1 0.53685427 +1 Pt -5.38493626 +1 -0.92521911 +1 -1.74164697 +1 Tv 8.08780608 +1 0.02395208 +1 -0.06407193 +1 Tv 2.62681385 +1 -3.61888255 +1 -6.78888729 +1 Tv 2.53918019 +1 7.64686321 +1 0.12696267 +1